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WHICH EPOXY IS BEST FOR YOUR APPLICATION?
Simply defined epoxy resins are polymer plastics that undergoes a chemical reaction or cross linking that converts from a liquid polymer to solid plastic. Epoxy resins belongs to sub classifications of plastics called thermoset polymers. Thermo-setting polymers typically are liquid resins that converts via chemical reaction into a solid plastic that cannot be reverted back into its original liquid state.Inversely thermo-plastics. are polymers, which its physical state can be modified either by heat, pressure or can be diluted using a solvent into either a liquid and back to solid back and forth numerous times with minimal physical change from its original physical structure; a good example of a thermoplastic polymer is candle wax which is typically a solid but can be converted into a liquid state either by temperature or diluted into solution using a solvent such as kerosene.
The use of an epoxy resin usually falls into two factors that will dictate its primary use.
MECHANICAL PERFORMANCE
CURED HARDNESS
The hardness testing of plastics is most commonly measured by the Shore (Durometer) test. The two Sore Durometer methods measure the resistance of the plastic toward indentation. Both scales provide an empirical hardness value that doesn't correlate to other properties or fundamental characteristics. Shore Hardness, using either the Shore A or Shore D scale, is the preferred method for rubbers/elastomers and is also commonly used for 'softer' plastics such as polyolefin, fluoropolymer, and vinyls. The Shore A scale is used for 'softer' rubbers while the Shore D scale is used for 'harder' ones. The shore A Hardness is the relative hardness of elastic materials such as rubber or soft plastics can be determined with an instrument called a Shore A durometer. If the indenter completely penetrates the sample, a reading of 0 is obtained, and if no penetration occurs, a reading of 100 results. The reading is dimension less.
The Shore hardness is measured with an apparatus known as a Durometer and consequently is also known as 'Durometer hardness'. The hardness value is determined by the penetration of the Durometer indenter foot to the sample. Because of the resilience of rubbers and plastics, the hardness reading my change over time - so the indentation time is sometimes reported along with the hardness number. The ASTM test number is ASTM D2240 while the analogous ISO test method is ISO 868. he results obtained from this test are a useful measure of relative resistance to indentation of various grades of polymers. However, the Shore Durometer hardness test does not serve ell as a predictor of other properties such as strength or resistance to scratches, abrasion, or wear, and should not be used alone for product design specifications.
Material
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Approximate
Shore A
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Approximate
Shore D
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Rubber
band, white eraser
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25-30
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-
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Pink
eraser
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35-45
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-
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Rubber
stamp
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40-55
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-
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Hard
eraser, inner tube
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45-65
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-
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Leather
belt, tire tread
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65-75
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-
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Rubber
shoe sole
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75-85
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25-30
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Tap
washer, skateboard wheel
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85-95
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30-40
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Garden
hose
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95-100
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40-50
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Hard
book cover
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-
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50-55
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Golf
ball
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-
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55-65
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Wood
yard stick
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-
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70-75
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White
board
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-
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75-80
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Bowling
ball, bone
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-
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85-90
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COMPRESSION STRENGTH
The compressive strength of a material is the compressive force per unit area that it n withstand. This is in contrast to the more commonly measured tensile strength. ASTM D695 is the standard test method in the USA. The figure below, from Quadrant Engineering Plastic Products, shows the test geometry.
Compressive strength test apparatus
North American plastics manufacturers
generally report compressive yield strength, the stress measured at the point
of permanent yield, zero slope, on the stress-strain curve. Ultimate
compressive strength is the stress required to rupture a specimen. Materials
such as most plastics that do not rupture can have their results reported as
the compressive strength at a specific deformation such as 1%, 5%, or 10% of
the test sample's original height.
The table below lists average compressive
strengths and compressive moduli for some filled and unfilled polymers. Typical Compressive Yield Strength and
Compressive Modulus of Polymers (A wide variation is possible between
specific grades).
Polymer Type
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Compressive Yield Strength (MPa)
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Compressive Modulus (GPa)
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ABS
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65
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2.5
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ABS + 30% Glass Fiber
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120
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8
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Acetal Copolymer
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85
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2.2
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Acetal Copolymer + 30%
Glass Fiber
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100
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7.5
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Acrylic
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95
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3
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Nylon 6
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55
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2.3
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Polyamide-Imide
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130
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5
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Polycarbonate
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70
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2.0
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Polyethylene, HDPE
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20
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0.7
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Polyethylene
Terephthalate (PET)
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80
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1
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Polyimide
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150
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2.5
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Polyimide + Glass
Fiber
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220
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12
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Polypropylene
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40
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1.5
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Polystyrene
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70
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2.5
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TENSILE STRENGTH FLEXURAL STRENGTH ELONGATION IMPACT DURABILITY
In general epoxy resin will react and polymerize at room temperature with the addition of a curing agent or catalyst. Higher mechanical performance epoxy resin systems typically requires special curing requirements to attain heat resistance of 250.
Higher mechanical performance epoxy resin system requires special consideration in handling such as processing higher viscosity resins, darker or more amber color and the need of external heat to induce polymerization.
Other factors such as ADHESION PERFORMANCE, CHEMICAL AND ENVIRONMENTAL RESISTANCE, ELECTRICAL CONDUCTANCE OR INSULATIVE PROPERTIES, LOAD BEARING RESISTANCE PERFORMANCE AT HIGH OR LOW TEMPERATURE, DIMENSIONAL STABILITY are also attributes of the cured mechanical performance of an epoxy resin system.
AESTHETIC PERFORMANCE
COLOR STABILITY
GLOSS AND SURFACE QUALITY
PIGMENTING OR TINTING FOR COLOR OPACITY
OUTDOOR DURABILITY AND RESISTANCE TO ENVIRONMENT FACTORS
Epoxy based polymers are one of the most versatile resins that can be modified into a multitude of applications
and engineered to specific application and use. It offers ease of use and generally safe handling process,
which makes it a versatile chemical compound that can be formulated to perform very specific task as demanded by the application.
Mechanical performance analysis
When designing a composite part there are many aspects that must be taken into consideration to insure its efficacy during use. Design, material selection, fabricating process and other implementation parameters must be carefully considered.
What is impact testing?
Impact testing is one of the most revealing test methods that demonstrate a material's ability to resist and withstand a high-rate of. Its behavior during and after the impact can define its maximum mechanical property and conditional limits upon its destruction. To answer this question, one must determine the load or type of stress that the resin must endure during the life of the fabricated part. Through analysis of its resistance and and conclusively its ultimate mechanical performance pass the point of destruction one can determine and establish parameters and designs that will involve the use of an epoxy resin as an, adhesive, coating or ultimately an integral part of the synergy of a composite.
Why is Impact Testing Important?
The impact resistance of an object provides the ultimate measure of its resistance to its definitive destruction. Governed by the many laws and dynamics of physics, a skilled chemist or materials engineer can determine the design equilibrium and ultimate performance by careful analysis of the material’s disassociation and the manner of its destruction. With this knowledge, other aspects of mechanical performance can be accurately derived and through skillful engineering one can determine:
MAX CLR is our line of very clear and color stable epoxy systems requiring absolute water clarity.
MAX BOND Product line is of epoxy - polyamide resin system demonstrating excellent mechanical properties suitable for marine and aeronautics construction. It is still an epoxy system but utilizes a very unique curing arrange that provides exceptional performance.
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